Tolylene-2,4-diisocyanate CAS#584-84-9
CAS Number: 584-84-9
Chemical Formula:C9H6N2O2
Synonyms:
Appearance: Colorless liquid
HS Code: 29291010
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
Products Description of Tolylene-2,4-diisocyanate CAS#584-84-9
Toluene diisocyanate (TDI), chemical formula (OCN)₂C₆H₃CH₃, presents as a water-white to pale yellow liquid with a sharp and pungent odor. It undergoes a reaction with water to produce carbon dioxide, has a specific gravity of 1.22 (greater than water), and is toxic when inhaled or ingested. It is a potent irritant to the skin and other tissues, especially the eyes. The TLV in air is 0.005 ppm, and the IDLH concentration is 10 ppm.
Parameters
Melting point | 20-22 °C(lit.) |
Boiling point | 124-126 °C18 mm Hg(lit.) |
density | 1.225 g/mL at 25 °C |
vapor density | 6 (vs air) |
vapor pressure | 0.03 mm Hg ( 25 °C) |
refractive index | n20/D 1.568(lit.) |
Fp | 250 °F |
storage temp. | 2-8°C |
solubility | Miscible with ether, acetone, benzene, carbontetrachloride and chlorobenzene. |
form | Liquid |
Specific Gravity | 1.225 |
color | Colorless |
Odor | Sharp, pungent odor detectable at 0.02 to 0.4 ppm |
explosive limit | 9.5% |
Water Solubility | reacts |
Sensitive | Moisture Sensitive |
Merck | 14,9530 |
BRN | 744602 |
Exposure limits | TLV-TWA 0.0355 mg/m3 (0.005 ppm) (ACGIH and NIOSH); STEL or ceiling/10 min 0.142 mg/m3 (0.02 ppm) (ACGIH, NIOSH, and OSHA); IDLH 71 mg/m3 (10 ppm) (NIOSH). |
Stability: | Stable, but decomposes in the presence of moisture. Also heat and light sensitive. Readily polymerizes in contact with base. Reacts with compounds containing active hydrogen. Incompatible with strong oxidizing agents. Corrodes some copper and aluminium alloys. |
InChIKey | DVKJHBMWWAPEIU-UHFFFAOYSA-N |
LogP | 3.43 at 22℃ |
CAS DataBase Reference | 584-84-9(CAS DataBase Reference) |
NIST Chemistry Reference | Benzene, 2,4-diisocyanato-1-methyl-(584-84-9) |
EPA Substance Registry System | Toluene-2,4-diisocyanate (584-84-9) |
Safety Information
Hazard Codes | T+ |
Risk Statements | 26-36/37/38-40-42/43-52/53 |
Safety Statements | 23-36/37-45-61 |
RIDADR | UN 2078 6.1/PG 2 |
WGK Germany | 2 |
RTECS | CZ6300000 |
F | 10-21 |
Autoignition Temperature | >619 °C |
TSCA | Yes |
HazardClass | 6.1 |
PackingGroup | II |
HS Code | 29291010 |
Hazardous Substances Data | 584-84-9(Hazardous Substances Data) |
Toxicity | Acute oral LD50 for rats 5,800 mg/kg, wild birds 100 mg/kg (quoted, RTECS, 1985). |
IDLA | 2.5 ppm |
Product Application of Tolylene-2,4-diisocyanate CAS#584-84-9
Toluene-2,4-diisocyanate (TDI) ranks among the most extensively utilized isocyanates. It is employed in the production of rigid and flexible urethane foams, elastomers, and coatings. Commercially, it is supplied either as a pure compound or as mixtures of 2,4- and 2,6-isomers, with typical ratios of 80:20 and 65:35. Occupational allergies constitute the primary cause of work-related respiratory illnesses worldwide, and TDI is a prominent respiratory sensitizer associated with the development of occupational asthma.
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